Influences of the Eu Concentration and the Milling Time on Photoluminescence Properties of Y2O3-H3BO3:Eu3+ Powders Prepared by Mechanical Alloying

서지정보

ㆍ발행기관 : 한국분말야금학회 ㆍ수록지정보 : 한국분말야금학회지 / 23권 / 2호
ㆍ저자명 : Hyun-Sic Gong, Hyun-Goo Kim

목차

1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
References

영어 초록

Y2O3–H3BO3:Eu3+ powders are synthesized using a mechanical alloying method, and their photoluminescence (PL) properties are investigated through luminescence spectrophotometry. For samples milled for 300 min, some Y2O3 peaks ([222], [440], and [622]) and amorphous formations are observed. The 300-min-milled mixture annealed at 800°C for 1 h with Eu = 8 mol% has the strongest PL intensity at every temperature increase of 100°C (increasing from 700 to 1200°C in 100°C increments). PL peaks of the powder mixture, as excited by a xenon discharge lamp (20 kW) at 240 nm, are detected at approximately 592 nm (orange light, 5Do → 7F1), 613 nm, 628 nm (red light, 5Do → 7F2), and 650 nm. The PL intensity of powder mixtures milled for 120 min is generally lower than that of powder mixtures milled for 300 min under the same conditions. PL peaks due to YBO3 and Y2O3 are observed for 300-min-milled Y2O3–H3BO3 with Eu = 8 mol% after annealing at 800°C for 1 h.

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